6. Javier Bardam as Anton Chigurh (No Country for Old Men)
Psychopathic hit-men definitely make great villains, but Anton Chigurh has got to be at the top of the list. Uncaring, remorseless and unrelenting. What more could you ask for in an intimidating villain? Well, throw in his ability to bounce back from gunshots and car wrecks and you end up with a waking nightmare.